کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
196317 459837 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrosynthesis and characterization of a poly(paraphenylene) deriving from p-fluoroanisole
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrosynthesis and characterization of a poly(paraphenylene) deriving from p-fluoroanisole
چکیده انگلیسی

The electrochemical oxidation of p-fluoroanisole (p-FA) in the solvent acetonitrile leads to oligomers and polymers of poly(paraphenylene) type. The electropolymerization process involves coupling reactions of the cation radicals intermediates. The obtained polymers are separated according to their chain length by selective precipitation in cyclohexane and ether. The corresponding structures are characterized by NMR, MS, FTIR, UV and XR diffraction. A preliminary physical study shows that the polymers are photoluminescent with a maximum emission in the near infrared.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 51, Issue 20, 25 May 2006, Pages 4309–4315
نویسندگان
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