کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
200690 460509 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A semi empirical compact equation of state for hard sphere fluids at any density
ترجمه فارسی عنوان
معادله فشرده نیمه تجربی برای مایعات کروی سخت در هر تراکم
کلمات کلیدی
تراکم بسته بندی، بستن بسته بندی تصادفی معادله ایالت، کره های سخت گسترش ویروسی، ضرایب ویروسی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

We propose a new semi empirical expression of the equation of state for a hard sphere fluid which is valid in the disordered phases over the whole density range below and above the freezing point. Starting from the existing numerical results for the virial coefficients, we elaborate a compact expression for the equation of state which is compatible both with the low and medium density behaviour (disordered stable phase) and with the asymptotic high density behaviour (disordered metastable phase). The resulting equation of state has a compact form and exhibits a simple pole at the close random packing density and a double pole at a density equal to 1. That equation of state only depends on the following quantities: the virial coefficients B2, B3 ,B4, which can be exactly computed, the random packing density ξ0, which is imposed by statistical geometry, and the residue of the pole in ξ0. The results are in a fairly good agreement with the numerical data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 421, 15 August 2016, Pages 9–15
نویسندگان
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