کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
201386 | 460546 | 2015 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chemical equilibrium for the reactive system acetic acid + n-butanol + n-butyl acetate + water at 308.15 K
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Chemical equilibrium (CE) for the quaternary reactive system of acetic acid–n-butanol–n-butyl acetate–water was studied at 308.15 K and atmospheric pressure. The experimental data on CE were considered in comparison with the data on liquid–liquid equilibrium: the CE is reached both in homogeneous and heterogeneous area of reactive mixture compositions. The crossing of CE and binodal surfaces is presented in a composition tetrahedron and a square of transformed composition variables. The thermodynamic constant of CE at 308.15 K was determined with the use of NRTL and UNIQUAC models.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 403, 15 October 2015, Pages 10–13
Journal: Fluid Phase Equilibria - Volume 403, 15 October 2015, Pages 10–13
نویسندگان
Artemiy Samarov, Pavel Naumkin, Alexander Toikka,