کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
203274 | 460644 | 2013 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Catechin sublimation pressure and solubility in supercritical carbon dioxide Catechin sublimation pressure and solubility in supercritical carbon dioxide](/preview/png/203274.png)
• New solubility data of (+)-catechin in SC-CO2 with ethanol (5 mol.%) as co-solvent.
• (+)-Catechin is a stable phenolic compound with very low sublimation pressure.
• Density based equations were found to fit the measured solubility data very well.
Solubility of (+)-catechin in SC-CO2 was measured at several temperatures (313.15, 323.15, 333.15 and 343.15 K) and pressure in the range of 12–26 MPa using ethanol as the co-solvent (5 mol.%). The experimental data were used for the correlation of density dependent solute solubility parameters. The equations of Chrastil, del Valle and Aguilera, Adachi and Lu, González, and Méndez-Santiago and Tejawere fitted very well for the solubility of (+)-catechin. The rate of mass loss of (+)-catechin showed that its sublimation pressure is very low, an indication of the stability of the compound. Thermogravimetric analysis was used to determine the sublimation pressure.
Solubility of (+)-catechin versus density of SC-CO2 at various temperature.Figure optionsDownload as PowerPoint slide
Journal: Fluid Phase Equilibria - Volume 358, 25 November 2013, Pages 220–225