کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
209232 461662 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrocracking of benzyloxybenzene as a lignite-related model compound over a novel solid acid
ترجمه فارسی عنوان
هیدروکراکینگ بنزیلوسیبنزن به عنوان یک ترکیب مدل مرتبط با لیگنیت بر روی یک اسید جامد جدید
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• A novel solid acid was prepared by impregnating trifluoromethanesulfonic acid (TFMSA) onto attapulgite powder (AP).
• Benzyloxybenzene (BOB) was mainly hydrocracked by TFMSA/AP without gaseous hydrogen.
• The proton transfer from TFMSA/AP to the oxygen atom in BOB could be the crucial step.
• TFMSA/AP significantly reduced the apparent activation energy of BOB hydrocracking.

A novel solid acid was prepared by impregnating trifluoromethanesulfonic acid (TFMSA) onto attapulgite powder (AP). Benzyloxybenzene (BOB) was used as a lignite-related model compound to evaluate the catalytic activity of TFMSA/AP for cleaving Calk–O bridged bonds in lignites. The results show that BOB was mainly hydrocracked to toluene, phenol, and (ethoxymethyl)benzene over TFMSA/AP in ethanol without adding gaseous hydrogen. In addition, ethanol participated in and significantly facilitated BOB hydrocracking. Based on the kinetic investigation, BOB hydrocracking over TFMSA/AP is absent of mass transfer limitations with the apparent activation energy of only 19.4 kJ mol− 1, which is far smaller than the dissociation energy (209.2 kJ mol− 1) of Calk–O bridged bond in BOB. The proton transfer directly from TFMSA/AP and/or via ethanol dehydrogenation to the oxygen atom of BOB could be the crucial step for BOB hydrocracking over TFMSA/AP.

The preparation of TFMSA/AP and BOB hydrocracking in ethanol over TFMSA/AP.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 146, 1 June 2016, Pages 110–115
نویسندگان
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