کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
210173 | 461699 | 2013 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Biodiesel production from soybean oil transesterification using tin oxide-supported WO3 catalysts Biodiesel production from soybean oil transesterification using tin oxide-supported WO3 catalysts](/preview/png/210173.png)
The transesterification of soybean oil with methanol to fatty acid methyl ester (FAME) was carried out using WO3/SnO2 solid as a heterogeneous acid catalyst. The effects of catalyst preparation parameters on the conversion to FAME were investigated. This WO3/SnO2 catalyst prepared by an impregnation method, with the WO3 loading amount of 30% and calcined at a temperature of 1173 K, showed the best catalytic activity. The maximum conversion to FAME of 79.2% was achieved after 5 h at 383 K when 30:1 M ratio of methanol to oil and 5 wt.% of catalyst were employed. The ability of the catalyst to esterify free fatty acids (FFAs) in feedstocks and its insensitivity to water exhibited the potential to prepare biodiesel from low-cost feedstocks. The solid catalyst can be reused for four runs without significant deactivation.
► The solid acid catalyst was effective in the soybean oil transesterification.
► The catalyst also showed activities in the esterification of free fatty acids.
► The catalytic activity and stability of the catalyst were investigated.
Journal: Fuel Processing Technology - Volume 109, May 2013, Pages 150–155