کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
212593 | 462056 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Separation of platinum(IV) and rhodium(III) from acidic chloride solution by ion exchange with anion resins Separation of platinum(IV) and rhodium(III) from acidic chloride solution by ion exchange with anion resins](/preview/png/212593.png)
Ion exchange experiments have been done to separate Pt(IV) and Rh(III) from chloride solution. Loading of the two metals into anion exchange resins, such as AG1-x2, AG1-x8 and AGMP-1 resin, was investigated in the HCl concentration range from 0.1 to 5 M. The concentration ratio of Pt and Rh in the chloride solution was fixed at 10:1. It was found that the loading of Pt into the resins followed Langmuir isotherm. The resins employed in this study had selectivity for Pt over Rh. The concentration of HCl had a pronounced effect on the loading of the two metals and Pt was effectively separated from Rh at low concentration of HCl. Batch experiments indicated that AG1-x8 resin was the most effective in separating Pt and Rh in our range. Continuous experiments with AG1-x8 resin verified that complete separation of Pt from Rh was possible. The loaded AG1-x8 resin was successfully regenerated by elution with thiourea.
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► AG resins were employed to separate Pt(IV) and Rh(III) from HCl solution.
► AG resins had a selectivity for Pt.
► Complete separation of Pt and Rh was verified by continuous experiments.
► The loaded resins could be regenerated by elution with thiourea.
Journal: Hydrometallurgy - Volumes 113–114, February 2012, Pages 200–204