کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
213076 462079 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solubility prediction of malachite in aqueous ammoniacal ammonium chloride solutions at 25 °C
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Solubility prediction of malachite in aqueous ammoniacal ammonium chloride solutions at 25 °C
چکیده انگلیسی

The solubility of malachite in the presence of ammonia, ammonium chloride and their mixed solution is calculated by a geochemical modeling code and is measured in a series of dissolution experiments using synthetic malachite at 25 °C. The simulated results show a good agreement with the experimental data gained at 25 °C. The predicted and experimental results indicate that the precipitate CuO limits the copper solubility in aqueous ammonia and Cu(OH)1.5Cl0.5 in aqueous ammonium chloride. For a mixed solution containing ammonia and ammonium chloride, highest copper solubility can be achieved by adjusting the [NH3]/[NH4Cl] ratio to about 2:1. The thermodynamic model presented rationalises the interactions between the different components and predicts the influence of changes in the concentration of ammonia and ammonium chloride on the copper solubility of malachite.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Hydrometallurgy - Volume 99, Issues 3–4, November 2009, Pages 231–237
نویسندگان
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