کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
213653 462120 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Identification of arsenato antimonates in copper anode slimes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Identification of arsenato antimonates in copper anode slimes
چکیده انگلیسی

It was found that, in copper electrolyte, the combination of As(V) and Sb(V) can form arsenato antimonic acid (AAAc) and, the reactions of AAAc with As(III), Sb(III), and Bi(III) can produce the precipitates of arsenato antimonates. During copper electrorefining, the As, Sb, and Bi deposited into the anode slime from the electrolyte are dominant in the forms of arsenato antimonates. It is extremely difficult to separate pure arsenato antimonates from copper anode slimes, while it is easy to synthesize arsenato antimonates using H2O2 to oxidize As(III) and Sb(III) in copper refining electrolyte. The composition and structure of the arsenato antimonates were determined with chemical analysis, IR and XRD techniques. The characteristic bands in the IR spectra of arsenato antimonates are δ of As–OH and Sb–OH at 1126.8 cm− 1, νas of As–OH at 1029.7 cm− 1, νas of As–OX(X = As, Sb) at 819.5 cm− 1, νas of Sb–OH at 618.4 cm− 1, νas of Sb–OY(Y = As, Sb) at 507.2 cm− 1, and νas of Sb–OBi at 470 cm− 1.The arsenato antimonates form irregular masses of amorphous structure because there are many OH groups in AAAc, the OH groups bond with As(III), Sb(III), and Bi(III) at random, which makes the arsenato antimonates formed in copper refining electrolyte have no fixed ratios for As/Sb/Bi. The formation of the arsenato antimonates can be expressed as follows:aH3AsO4 + bH[Sb(OH)6] + cMeO + →MecAsaSbbO(3a+5b+c/2+1)H(a+5b−2c+2)·xH2O + cH+ + (a + b + c / 2 − 1 − x)H2O, where Me = As(III), Sb(III) and Bi(III); a ≥ 1, b ≥ 1, c ≤ (3a + b)

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Hydrometallurgy - Volume 84, Issues 3–4, November 2006, Pages 211–217
نویسندگان
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