کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
214931 1426212 2016 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Volumetric properties of binary mixtures of {difluoromethane (R32) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at temperatures from 283.15 K to 363.15 K and pressures up to 100 MPa
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Volumetric properties of binary mixtures of {difluoromethane (R32) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at temperatures from 283.15 K to 363.15 K and pressures up to 100 MPa
چکیده انگلیسی


• Densities of R32+R1234ze(E) mixtures were measured with a vibrating-tube densimeter.
• Densities of mixtures were conducted from (283 to 363) K, at pressures up to 100 MPa.
• Excess molar volumes were correlated with the Redlich–Kister equation.

Values of experimental density of difluoromethane (R32) and five compositions of {R32 + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} binary mixtures are reported over the temperature range from 283 K to 363 K and at pressures up to 100 MPa with a vibrating-tube densimeter. The excess molar volumes were calculated from experimental results and fitted to the Redlich–Kister equation. The maximum standard deviation and average standard deviations of the experimental and calculated values of excess molar volume from Redlich–Kister equation are 0.07789 cm3·mol−1 and 0.01645 cm3·mol−1, respectively.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 101, October 2016, Pages 54–63
نویسندگان
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