کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
216763 | 1426303 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Density and viscosity of pyridinium-based ionic liquids and their binary mixtures with water at several temperatures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Densities and viscosities of two pyridinium-based ionic liquids, 1-butylpyridinium tetrafluoroborate [BuPy][BF4] and 1-octylpyridinium tetrafluoroborate [OcPy][BF4], and their binaries with water at atmospheric pressure and temperatures from (283.15 to 348.15) K were determined. The densities and viscosities of pure ionic liquids were correlated successfully by empirical equations. The Vogel–Fulcher–Tammann equations can fit the experimental viscosities for pure and binary of both IL systems. Excess molar volume and viscosity deviation were calculated for the binaries. The excess molar volumes have positive deviation from ideal solution while the viscosity deviations have negative values.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 41, Issue 3, March 2009, Pages 323–329
Journal: The Journal of Chemical Thermodynamics - Volume 41, Issue 3, March 2009, Pages 323–329
نویسندگان
Babak Mokhtarani, Ali Sharifi, Hamid Reza Mortaheb, Mojtaba Mirzaei, Morteza Mafi, Fatemeh Sadeghian,