کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217136 1426299 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The heat capacities and thermodynamic properties of NiAl2O4 and CoAl2O4 measured by adiabatic calorimetry from T = (4 to 400) K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The heat capacities and thermodynamic properties of NiAl2O4 and CoAl2O4 measured by adiabatic calorimetry from T = (4 to 400) K
چکیده انگلیسی

The low-temperature heat capacity of NiAl2O4 and CoAl2O4 was measured between T = (4 and 400) K and thermodynamic functions were derived from the results. The measured heat-capacity curves show sharp anomalies peaking at around T = 7.5 K for NiAl2O4 and at T = 9 K for CoAl2O4. The exact cause of these anomalies is unknown. From our results, we suggest a standard entropy for NiAl2O4 at T = 298.15 K of (97.1 ± 0.2) J · mol−1 · K−1 and for CoAl2O4 of (100.3 ± 0.2) J · mol−1 · K−1.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 41, Issue 7, July 2009, Pages 842–848
نویسندگان
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