کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
217353 | 1426327 | 2007 | 12 صفحه PDF | دانلود رایگان |
The densities of binary mixtures of formamide (FA) with ethanol, 1-propanol, 1,2-ethanediol, and 1,2-propanediol, including those of pure liquids, over the entire composition range were measured at temperatures (293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and atmospheric pressure. From the experimental data, the excess molar volume, VmE, partial molar volumes, V¯m,1andV¯m,2, over the whole composition range and V¯m,1∘andV¯m,2∘ at infinite dilution, and excess partial molar volumes, V¯m,1EandV¯m,2E, over the whole composition range and V¯m,1∘EandV¯m,2∘E at infinite dilution were calculated. The variation of these parameters with composition and temperature of the mixtures have been discussed in terms of molecular interaction in these mixtures. The observed trends in VmE values indicate the presence of specific interactions between FA and alkanol molecules. The VmE values follows the order: ethanol < 1-propanol < 1,2-ethanediol < 1,2-propanediol. It is observed that the VmE values depend upon the number of hydroxyl groups and alkyl chain length in these alkanol molecules.
Journal: The Journal of Chemical Thermodynamics - Volume 39, Issue 3, March 2007, Pages 462–473