کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
222525 464276 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Utilization of glycerol for the production of glycerol carbonate through greener route
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Utilization of glycerol for the production of glycerol carbonate through greener route
چکیده انگلیسی

Availability of glycerol is increased in recent years due to production of biodiesel. Glycerol carbonate, an important compound, can be manufactured using glycerol as a raw material. This work describes the synthesis of glycerol carbonate from glycerol via an enzymatic transesterification reaction using dimethyl carbonate as co-substrate and in presence as well as in absence of solvent. It has been observed that the glycerol and methanol (generated during transesterification) showed an inhibitory effect on the enzyme activity. In presence of solvent i.e. tertiary butanol, the rate of reaction is increased due to higher solubility of glycerol in it. Methanol was removed using molecular sieves. After the optimization of various parameters affecting the reaction, 94.85% conversion of glycerol was achieved with 1.5:1 molar ratio of dimethyl carbonate to glycerol and catalyst amount of 22.02% Novozym 435 at 60 °C in 14 h.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Chemical Engineering - Volume 1, Issue 4, December 2013, Pages 1231–1236
نویسندگان
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