Measurement of tritium permeation in flibe (2LiF–BeF2)

This paper reports on the experimental investigation of tritium permeation in flibe (2LiF–BeF2) at the Safety and Tritium Applied Research facility of the Idaho National Laboratory. A stainless steel cell formed by two independent volumes separated by a 2-mm thick nickel membrane is maintained at temperatures between 500 and 700 °C. A controlled amount of T2 gas is flown in excess of argon in the source volume in contact with the bottom side of the nickel membrane, while a layer of molten salt is in contact with the top side. The tritium permeating above the liquid surface is carried by an argon flow to a diagnostic system comprised of a quadrupole mass spectrometer, a gas chromatographer and a proportional counter. Tritium permeability in flibe as a function of temperature is determined by the measured permeation flow rates reached in steady-state conditions, while the diffusivity is determined by fitting the transient process with the analytical solution for the diffusion process. As a result, the solubility of tritium in flibe as a function of temperature is also determined.