کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
28220 44066 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and optical properties of Ag/PPy composite colloids
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
Preparation and optical properties of Ag/PPy composite colloids
چکیده انگلیسی

Ag/PPy (polypyrrole) composite colloids were prepared through the reaction of silver nitrate with pyrrole solution in DMF either in the dark, or under the irradiation of femtosecond laser (fs) pulse or UV lamp. The UV–vis spectra of the nanocomposite colloid display an intense absorption band around 620 nm, accompanied by a weak one around 470 nm. The colors and optical absorption spectra of as-synthesized colloids can be reversibly tuned between blue and red, corresponding to absorption band of 620 nm and 526 nm, within few seconds by adding base and acid solutions or gases in turn into the composite colloid suspension. In addition, excess of H+ solution enhanced the absorption band around 470 nm and, at the same time, depressed that around 620 nm. The possible mechanism for the formation and optical absorption properties of the Ag/PPy composite colloid was proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 187, Issues 2–3, 15 April 2007, Pages 146–151
نویسندگان
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