کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
28544 | 44080 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Gradual change of one- and two-photon absorption properties in solution-Protonation of 4-N,N-dimethylamino-4â²-aminoazobenzene
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Gradual change of one- and two-photon absorption properties in solution-Protonation of 4-N,N-dimethylamino-4â²-aminoazobenzene Gradual change of one- and two-photon absorption properties in solution-Protonation of 4-N,N-dimethylamino-4â²-aminoazobenzene](/preview/png/28544.png)
چکیده انگلیسی
Linear (one-photon) and nonlinear (two-photon) spectral properties of 4-N,N-dimethylamino-4â²-aminoazobenzene have been investigated under protonation in DMSO/water solvent mixtures. Observed spectral changes have been discussed in terms of ammonium-azonium tautomerism. The corresponding tautomeric constants have been determined for the first time for such kind of tautomeric equilibria. The process of protonation leads to changes of the two-photon absorption properties, suggesting that such process could be used as a tool for change of third-order nonlinear optical activity in solution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 181, Issues 2â3, 31 July 2006, Pages 274-282
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 181, Issues 2â3, 31 July 2006, Pages 274-282
نویسندگان
Liudmil Antonov, Kenji Kamada, Daniela Nedeltcheva, Koji Ohta, Fadhil S. Kamounah,