کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
28670 44085 2006 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Photophysical behaviour of 4-hydroxy-3,5-dimethoxybenzoic acid in different solvents, pH and β-cyclodextrin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
Photophysical behaviour of 4-hydroxy-3,5-dimethoxybenzoic acid in different solvents, pH and β-cyclodextrin
چکیده انگلیسی

Effect of solvents, buffer solutions of different pH and β-cyclodextrin on the absorption and fluorescence spectra of 4-hydroxy-3,5-dimethoxybenzoic acid [HDMB] have been investigated. The inclusion complex of β-CD with HDMB is investigated by UV–vis, fluorometry, FTIR, 1H NMR, scanning electron microscope (SEM) and semiempirical methods. The thermodynamic parameters (ΔG, ΔH and ΔS) of inclusion process are also determined. The Stokes shifts of HDMB correlated with various solvent polarity scales, suggest that the HDMB molecule is more polar and the change in dipole moment is large in the S1 state. The pKa and pKa* values of neutral-monoanion and monoanion–dianion equilibria have been determined with fluorimetric titrations and Förster cycle methods and compared. β-Cyclodextrin studies shows that HDMB forms a 1:1 inclusion complex with β-CD. A mechanism is proposed to explain the inclusion process.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 177, Issues 2–3, 25 January 2006, Pages 144–155
نویسندگان
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