کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4412763 | 1307651 | 2009 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electroanalytical method for determination of lead(II) in orange and apple using kaolin modified platinum electrode Electroanalytical method for determination of lead(II) in orange and apple using kaolin modified platinum electrode](/preview/png/4412763.png)
This paper reports on the use of platinum electrode modified with kaolin (K/Pt) and square wave voltammetry for analytical detection of trace lead(II) in pure water, orange and apple samples. The electroanalytical procedure for determination of the Pb(II) comprises two steps: the chemical accumulation of the analyte under open-circuit conditions followed by the electrochemical detection of the preconcentrated species using square wave voltammetry. The analytical performances of the extraction method has been explored by studying the incubating time, and effect of interferences due to other ions. During the preconcentration step, Pb(II) was accumulated on the surface of the kaolin. The observed detection and quantification limits in pure water were 3.6 × 10−9 mol L−1 and 1.2 × 10−8 mol L−1, respectively. The precision of the method was also determined; the results was 2.35% (n = 5).
Journal: Chemosphere - Volume 76, Issue 8, August 2009, Pages 1130–1134