کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4413186 | 1307668 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidative degradation of 1,5-naphthalenedisulfonic acid in aqueous solutions by microwave irradiation in the presence of H2O2
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم محیط زیست
شیمی زیست محیطی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Sulfonated aromatic pollutants such as Armstrong's acid, or 1,5-naphthalenedisulfonic acid (NDS), are recalcitrant to environmental breakdown and microbial treatment. This study investigated the effects of H2O2 concentration, pH, microwave (MW) power and irradiation time on the oxidative degradation of NDS in aqueous solutions. The formation of hydroxyl radicals as the active oxidant was confirmed by electron paramagnetic resonance spin trapping. A combination of both H2O2 and MW heating proved essential for NDS degradation. Degradation factors of f ⩾ 70% were obtained after about 20 min of irradiation at [H2O2]:[NDS] ratios = 10. Acidic conditions were found to be more favorable to the degradation of NDS, and the process follows pseudo-first-order kinetics. Attempts to scale-up the process using a conventional MW reactor provided less striking results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemosphere - Volume 74, Issue 10, March 2009, Pages 1309-1314
Journal: Chemosphere - Volume 74, Issue 10, March 2009, Pages 1309-1314
نویسندگان
Mauro Ravera, Alessandra Buico, Fabio Gosetti, Claudio Cassino, Davide Musso, Domenico Osella,