Arsenate adsorption on three types of granular schwertmannite

Schwertmannite was synthesized on a 2 m3-scale and fabricated to irregular, cylindrical and spherical shape granules using drum granulation, extrusion and spray coating, respectively. The granules were systematically evaluated for As(V) removal from drinking water in terms of both performance and safety. The irregular and cylindrical shape granules (IS and CS) had larger schwertmannite loadings, higher porosity, more abundant pore structure and larger micropore volumes than those with a spherical shape (SS). As(V) adsorption kinetics on IS, CS and SS schwertmannite granules followed a pseudo-second order rate equation and two-stages of intraparticle diffusion. The rate parameters were in an order of IS > CS > SS granules. The faster uptake kinetics of the IS granules was due to their largest pore volume and interparticle porosity. Furthermore, adsorption capacities of 34, 21 and 5 mg/g, for IS, CS and SS granular schwertmannite samples were achieved at an initial As(V) concentration of 20 mg/L and adsorbent dose of 0.5 g/L. IS and CS samples performed much better over a wide pH range versus SS samples. Except for humic acid, PO43− and SiO44− did not inhibit As(V) adsorption on IS and CS granular specimens. SS samples worked poorly even in the absence or presence of co-existing anions. Regeneration was achieved using 0.1 M NaOH. The recycled IS and CS granular specimens can be used for 4 different cycles with no or nominal loss of adsorption capacity. Column experiments were also conducted. The IS, CS and SS granular specimens treated 8100, 4200 and 120 bed volumes (BVs) of contaminated water. No heavy metals leached from the packed granular adsorbent and appeared in the column effluent. Furthermore, the toxicity characteristic leaching procedure (TCLP) showed that the spent IS and CS granules were inert and could safely be disposed of in landfills. In short, irregular-shaped granules (IS) fabricated by drum granulation is a good candidate for arsenic removal from drinking water with a high future application potential.

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► Granular schwertmannite was successfully fabricated by three methods.
► Drum granulation-made granules have the highest capacity with fast kinetics.
► The spent granules can be easily regenerated with dilute NaOH solution.
► The granules were safe according to the TCLP tests.