کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
45005 46393 2016 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective catalytic reduction of NO by NH3 with WO3-TiO2 catalysts: Influence of catalyst synthesis method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selective catalytic reduction of NO by NH3 with WO3-TiO2 catalysts: Influence of catalyst synthesis method
چکیده انگلیسی


• WO3-TiO2 catalysts were prepared by co-precipitation at varying pH values.
• Catalysts made by co-precipitation have two distinct surface WOx species.
• SCR activity of co-precipitated WO3-TiO2 catalysts is higher at high preparation pH.
• Co-precipitated catalysts have higher ammonia capacity than incipient wetness analogs.

A series of supported WO3/TiO2 catalysts was prepared by a new synthesis procedure involving co-precipitation of an aqueous TiO(OH)2 and (NH4)10W12O41*5H2O slurry under controlled pH conditions. The morphological properties, surface WOx molecular structures, surface acidity and surface chemistry of the co-precipitated WO3/TiO2 catalysts were determined with BET, in situ Raman, in situ IR, steady-state NO/NH3/O2 SCR and NO/NH3-temperature-programmed surface reaction (TPSR) spectroscopy, respectively. Time-resolved isotopic 18O–16O exchange with IR spectroscopy demonstrated that tungsten oxide was present as surface WOx sites on the TiO2 support with mono-oxo O = WO4 coordination. In contrast to previous studies employing impregnation synthesis that found only surface one mono-oxo O = WO4 site (1010–1016 cm−1) on TiO2, the co-precipitation procedure resulted in the formation of two distinct surface WOx sites: mono-oxo O = WO4 (∼1012–1014 cm−1) and a second mono-oxo O = WO4 (∼983–985 cm−1). The new surface mono-oxo O = WO4 (∼983–985 cm−1) site is thought to be associated with surface defects on the co-precipitated titania support. The co-precipitated catalysts exhibited slightly enhanced SCR reactivity that is thought to be related to the presence of the new surface O = WO4 sites. Additional factors, however, may also be contributing. This is the first study that attempts to relate the molecular level structural properties of co-precipitated WO3-TiO2 catalysts with their surface reactivity for SCR.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 188, 5 July 2016, Pages 123–133
نویسندگان
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