کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
45597 | 46416 | 2015 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis of glycerol carbonate from the transesterification of dimethyl carbonate with glycerol using DABCO and DABCO-anchored Merrifield resin Synthesis of glycerol carbonate from the transesterification of dimethyl carbonate with glycerol using DABCO and DABCO-anchored Merrifield resin](/preview/png/45597.png)
• DABCO afforded much higher GLC yield than other polyamines.
• DABCO is successfully immobilized onto Merrifield resin ([p-DABCO]Cl).
• [p-DABCO]Cl showed high transesterification activity and reusability.
• Mechanism of the transesterification of glycerol with DMC was investigated.
Both DABCO (1,4-diazabicyclo[2.2.2]octane) and Merrifield resin-anchored DABCO ([p-DABCO]Cl), prepared from the reaction of DABCO and Merrifield resin, were found to exhibit high activities for the transesterification of dimethyl carbonate (DMC) with glycerol to produce glycerol carbonate (GLC). FT-IR and NMR spectroscopic results suggest that such a high transesterification activity of DABCO could be attributed to its superior ability to activate glycerol via a strong hydrogen bond formation between a hydroxyl group of glycerol and an amino group of DABCO. Meanwhile, the activation of glycerol by [p-DABCO]Cl proceeds mainly through the hydrogen bond interaction between a hydroxyl group or groups of glycerol and Cl− of [p-DABCO]Cl. The catalytic activity of [p-DABCO]Cl was maintained up to 5 reuses, demonstrating that [p-DABCO]Cl could be used as a recyclable heterogeneous catalyst.
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Journal: Applied Catalysis B: Environmental - Volume 165, April 2015, Pages 642–650