Fe-doped ceria solids synthesized by the microemulsion method for CO oxidation reactions

A series of Ce–Fe mixed oxides as well as the pure oxides were synthesized by the microemulsions method. The solid solution formation was established for all the Fe-doped systems and only a hardly noticeable segregation of α-Fe2O3 was appreciated for the solid with the maximum iron content (50 at.% Fe). The oxygen exchange is improved for all the Fe-doped systems; however the 10 at.% Fe appears as the optimal iron content for achieving the maximum oxygen vacancies concentration and the higher reducibility efficiency. The CO oxidation (TOX, PROX) is especially achieved for the solids with the lower iron contents but with a superior oxygen vacancies proportion. These Ce–Fe systems prepared from microemulsions are very attractive to be considered as supports for depositing active phases capable of enhancing oxygen exchange ability of the whole system, allowing higher CO oxidation abilities.

The synthesis of Fe-doped ceria oxides was carried out by microemulsions method, employing different Fe atomic percentages (at.%). The 10 at.% Fe allows obtaining Ce–Fe solid solution with the higher oxygen vacancies content. This system presents the higher CO conversion during the TOX and PROX reactions.Figure optionsDownload as PowerPoint slideHighlights
• A series of Ce–Fe mixed oxides were synthesized by the microemulsions method.
• Solid solution formation was established for all the Fe-doped systems.
• The oxygen exchange is improved for all the Fe-doped systems.
• The 10 at.% Fe allows obtaining the maximum oxygen vacancies concentration.