کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4766730 | 1424107 | 2017 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
TiO2 Microflowers Assembled by 6-nm Single-Crystal Stranded Wires with Improved Photoelectrochemical Performances
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
As the diffusion length of charge carriers in TiO2 is around 10Â nm, it would be an efficient way to increase the photocatalytic properties by controlling the size within 10Â nm. Herein, TiO2 microflowers assembled by 6-nm single-crystal stranded wires grown on Ti foam (TiO2-SWs/TF) were synthesized which facilated electron transfer rate with a photocurrent of 0.33Â mAÂ cmâ2 compared to that of the P25/TF (0.06Â mAÂ cmâ2). A photoelectrochemical (PEC) system combining degradation of bisphenol A and H2 production was constructed based on the as-obtained TiO2-SWs/TF as photoanode and Pt wire as cathode. This PEC system exhibited excellent ability for simultaneous bisphenol A degradation and H2 production, giving a 94% bisphenol A degradation efficiency within 60Â min at 1.2 vs (Ag/AgCl) V with power consumption of only 0.02 kWh mâ3. The excellent PEC degradation of bisphenol A by the TiO2-SWs/TF could mainly be ascribed to the fast electron transfer via the 6-nm ultrathin wires and synergetic effect of photocatalysis and electrochemical process. Two pathways for PEC degradation of bisphenol A were proposed based on the intermediates identified by Ultra Performance liquid chromatography-quadruple-time of flight-mass spectrometry (UPLC-Q-TOF-MS).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 250, 1 October 2017, Pages 117-123
Journal: Electrochimica Acta - Volume 250, 1 October 2017, Pages 117-123
نویسندگان
Chunlei Liu, Wei Zhou, Li Yu, Gong Zhang, Jiuhui Qu, Huijuan Liu,