کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767169 | 1424119 | 2017 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Monitoring of epitaxial graphene anodization
ترجمه فارسی عنوان
نظارت بر آنودایزر گرافن اپیتاکسیال
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کلمات کلیدی
گرافن اپیتاکسالی، گرافن یکپارچه، آنودایزگی، سینتیک الکترودها، طیف سنجی رامان، ولتاژ سنجی، طیف سنجی امپدانس الکتروشیمیایی،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Anodization of a graphene monolayer on silicon carbide was monitored with electrochemical impedance spectroscopy. Structural and functional changes of the material were observed by Raman spectroscopy and voltammetry. A 21 fold increase of the specific capacitance of graphene was observed during the anodization. An electrochemical kinetic study of the Fe(CN)63â/4â redox couple showed a slow irreversible redox process at the pristine graphene, but after anodization the reaction rate increased by several orders of magnitude. On the other hand, the Ru(NH3)63+/2+ redox couple proved to be insensitive to the activation process. The results of the electron transfer kinetics correlate well with capacitance measurements. The Raman mapping results suggest that the increased specific capacitance of the anodized sample is likely due to a substantial increase of electron doping, induced by defect formation, in the monolayer upon anodization. The doping concentration increased from less than 1Â ÃÂ 1013 of the pristine graphene to 4-8Â ÃÂ 1013 of the anodized graphene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 238, 1 June 2017, Pages 91-98
Journal: Electrochimica Acta - Volume 238, 1 June 2017, Pages 91-98
نویسندگان
Mikhail Yu. Vagin, Alina N. Sekretaryova, Ivan G. Ivanov, Anna HÃ¥kansson, Tihomir Iakimov, Mikael Syväjärvi, Rositsa Yakimova, Ingemar Lundström, Mats Eriksson,