کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767381 | 1424132 | 2017 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical Behavior of Graphite Anode in LiF-NaF-KF Eutectic with YF3
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The electrode reactions and electrolysis process of graphite anode were investigated in LiF-NaF-KF (FLiNaK, 46.5-11.5-42.0Â mol%) eutectic with YF3 at 823Â K. Two different types of reactions were observed on graphite anode. The graphite was oxidized to carbon mono- and dioxide in a potential range of 0-2Â V (vs. Ni2+/Ni, similarly hereinafter), and carbon fluorides were generated when the potential fell into 6-8Â V. In addition, some fluoride products could be reduced at about â0.22Â V during reverse cyclic voltammetry scan, which has never been reported. Anode potential fluctuation was found between 6 and 8Â V during galvanostatic electrolysis due to the formation of gaseous products as well as change of anode surface area and current density. Both Raman and X-ray photoelectron spectroscopy were employed to probe the chemical states of fluorination/oxidation products on graphite anode after electrolysis. The formation of fluorocarbon species is responsible for the disorder on graphite surface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 392-398
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 392-398
نویسندگان
Lifang Tian, Wei Huang, Feng Jiang, Haiyang Zheng, Tiejian Zhu, Changfeng She, Xianbin Wang, Dewu Long, Yu Gong, Guozhong Wu, Qingnuan Li,