کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767394 | 1424132 | 2017 | 42 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Porous NiCo Diselenide Nanosheets Arrayed on Carbon Cloth as Promising Advanced Catalysts Used in Water Splitting
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
we report the synthesis of porous NiCo diselenide nanosheets arrayed on carbon cloth (CC) via ion exchange with a hydroxide precursor. This bind-free three-dimensional (3D) architecture possesses the huge specific surface area and facilitates ion transport and charge transfer, leading to a superior performance in water splitting as a bifunctional catalyst for both H2 and O2 evolution reaction (HER and OER). The as-prepared NiCo diselenide/CC composites show a high HER capability in 0.5 M H2SO4 solution with a Tafel slope as small as 31.6 mV·decâ1. They offer a HER current of 10 mA·cmâ2 at a low overpotential of 108 mV. Their OER efficiency is also remarkable in 1 M KOH solution with a small Tafel slope of 42.3 mV·decâ1 and a low overpotential of 258 mV at 10 mA·cmâ2. This 3D porous NiCo diselenide nanosheet array holds a promise as an attractive alternative to precious catalysts of water splitting with high activity and long-term stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 503-513
Journal: Electrochimica Acta - Volume 225, 20 January 2017, Pages 503-513
نویسندگان
Xudan Wang, Yuanyuan Zheng, Junhua Yuan, Jianfeng Shen, Jianguo Hu, Ai-jun Wang, Lanju Wu, Li Niu,