کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767776 | 1424141 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical Exfoliation of Graphite: Effect of Temperature and Hydrogen Peroxide Addition
ترجمه فارسی عنوان
لایه برداری الکتروشیمیایی گرافیت: اثر دما و افزودن پراکسید هیدروژن
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Controlling the defect density in graphene is critical to manipulate materials properties and functionality through synthesis and processing. In this work, graphene was prepared by electrochemical exfoliation method at different temperatures from 25 to 95 °C with and without the addition of H2O2. The effect of both the exfoliation temperature and H2O2 addition on governing the defect density and oxygen functional groups in graphene was investigated using Raman spectroscopy analysis and thermogravimetric analysis (TGA), respectively. The number of defects, which can be edge defect or oxygen functional groups, decreases with the increase of exfoliation temperature from 25 to 95 °C. This can be explained by nucleophilicity of hydroxyl ions and peroxide ions. The thermal stability of the as-synthesized graphene increases with increasing exfoliation temperature and the amount of H2O2 addition. Transmission electron microscopy (TEM) was performed to characterize the morphology and the layer number of the as-synthesized graphene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 216, 20 October 2016, Pages 253-260
Journal: Electrochimica Acta - Volume 216, 20 October 2016, Pages 253-260
نویسندگان
Shaikh T. Hossain, Ruigang Wang,