کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4979131 | 1453021 | 2018 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dissipation behavior and residue distribution of fluazaindolizine and its seven metabolites in tomato ecosystem based on SAX SPE procedure using HPLC-QqQ-MS/MS technique
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کلمات کلیدی
PHIMDSMRLsDCsLOQsResidue distributionRSDs - RSD هاrelative standard deviations - انحراف استاندارد نسبیMaximum Residue Limits - حداکثر حد مجازMolecular dynamics - دینامیک ملکولی یا پویایی مولکولیGood Agricultural Practices - روش های کشاورزی خوبGAP - شکافPre-harvest interval - فاصله قبل از برداشتLODs - لد هاLimits of quantification - محدودیت اندازه گیریlimits of detection - محدودیت های تشخیص
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dissipation behavior and residue distribution of fluazaindolizine and its seven metabolites in tomato ecosystem based on SAX SPE procedure using HPLC-QqQ-MS/MS technique Dissipation behavior and residue distribution of fluazaindolizine and its seven metabolites in tomato ecosystem based on SAX SPE procedure using HPLC-QqQ-MS/MS technique](/preview/png/4979131.png)
چکیده انگلیسی
Fluazaindolizine suspension concentrate (500 g Lâ1 SC), as a pre-commercialized product, was firstly investigated under open-field conditions. A sensitive method for simultaneous determination of fluazaindolizine and seven metabolites (IN-QEK31, IN-F4106, IN-A5760, IN-UJV12, IN-UNS90, IN-QZY47 and IN-TMQ01) was established and validated using HPLC-QqQ-MS/MS technique. The LOQs of these pollutants in tomato were 0.01 mg kgâ1, and their recoveries were 81.1%-117% with the relative standard deviations (RSDs < 11.8%). The dissipation behaviours of fluazaindolizine in soil followed first-order kinetics with the half lives of 4.6-32.4 days, whilst the residues in plant were below its LOQ after 7 days. The fluazaindolizine residues in soil were below 0.963 mg kgâ1, based on root irrigation applications (50-75 mg a.i. per plant) twice and pre-harvest interval (PHI, 3 days), while the residues of IN-QEK31, IN-F4106 and IN-A5760 were below 3.9 mg kgâ1, excluding other four metabolites ( < 0.01 mg kgâ1). The residues of fluazaindolizine in tomato were below 0.01 mg kgâ1, and IN-QEK31 remained 0.135 mg kgâ1. The current study could not only guide reasonable usage of the formulation, but also facilitate the setting of residue definition and its maximum residue limits (MRLs) of fluazaindolizine in tomato.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 342, 15 January 2018, Pages 698-704
Journal: Journal of Hazardous Materials - Volume 342, 15 January 2018, Pages 698-704
نویسندگان
Xiaoxin Chen, Xi Li, Kyongjin Pang, Xueqi Fan, Yecheng Ma, Jiye Hu,