Development, comparison and application of sorbent-assisted accelerated solvent extraction, microwave-assisted extraction and ultrasonic-assisted extraction for the determination of polybrominated diphenyl ethers in sediments

- SA-UAE, SA-ASE and SA-MAE were optimized for the analysis of PBDEs in sediments.
- Developed SA-methods provided comparable performances and were validated by SRM-1944.
- SA-methods development starts from fully extraction, then optimization of sorbents.
- Application on environmental samples approved the feasibility of developed method.

Fast and selective analytical methods were developed based on sorbent-assisted mechanism and microwave-assisted extraction (SA-MAE), accelerate solvent extraction (SA-ASE) and ultrasonic-assisted extraction (SA-UAE) for the determination of polybrominated diphenyl ethers (PBDEs) in sediments. The experimental parameters, such as extraction conditions and sorbent amounts, were optimized according to Taguchi Orthogonal Arrays. The accuracy of developed SA-methods was a satisfactory ranging from 71% to 118%. The inter/intra-day RSDs were <10% indicating a good method precision. The limits of quantification (LOQ) for target BDEs were ≤1.0 ng/g dry weight (dw) with an exception of BDE 209 which was 10.0 ng/g dw. The proposed methods were validated by the analysis of PBDEs in standard reference materials (SRM 1944) and the method performances were compared with each other. The results approved the feasibility of SA-methods for PBDEs analysis in sediments. Meanwhile, the optimization processes indicated the mixed sorbents mainly worked on matrix effects elimination. The compositions of sorbents deserved careful optimization because different characteristics of the matrix and extraction intensity may produce various matrix effects. In addition, the developed SA-ASE method was successfully applied on real environmental samples collected from a typical polluted area. The data and calculation suggested local environmental contamination pattern and potential pollution source.