کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5159908 | 1501667 | 2017 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and structural characterization of a dimethylformamide bound dioxouranium(VI) salen based complex with propylene linkage
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A dimethylformamide bound mononuclear dioxouranium(VI) salen based complex with propylene linkage is prepared from a salen ligand, H2L, 2,2-(1E,1E)-(2,2-dimethylpropane-1,3-diyl)bis(azanylylidene)bis(methanylylidene)diphenol. The structure of the reported uranyl complex is established by elemental analysis (C, H, N), FT-IR and NMR spectroscopic methods, and single crystal X-ray diffraction measurements. The X-ray diffraction analysis shows that the crystal is monoclinic with space group P21/n (no. 14), a = 7.99198(6) Ã
, b = 12.14896(9) Ã
, c = 23.76987(19) Ã
, β = 97.4163(7)°. Furthermore, to obtain insights into the structure, DFT calculations have been made employing 6-31G (d,p) and GENECP basic sets. The findings obtained from the theoretical calculations are quite close with the results obtained from the experimental data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1150, 15 December 2017, Pages 395-403
Journal: Journal of Molecular Structure - Volume 1150, 15 December 2017, Pages 395-403
نویسندگان
Mohammad Azam, Saud I. Al-Resayes, Mahboob Alam, Nader Talmas M. Albaqami, Soonheum Park, Agata Trzesowska-Kruszynska, Rafal Kruszynski,