کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5160983 1501691 2016 17 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Two new complexes of Lanthanide(III) ion with the N3O2-donor Schiff base ligand: Synthesis, crystal structure, and magnetic properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Two new complexes of Lanthanide(III) ion with the N3O2-donor Schiff base ligand: Synthesis, crystal structure, and magnetic properties
چکیده انگلیسی
Two rare earth coordination complexes, [Dy(DAPBH)NO3(H2O)2]⋅(NO3)2 (1), La(DAPBH)(NO3)3 (2) (where DAPBH = 2, 6-diacetylpyridine benzoyhydrazone), have been synthesized and characterized. Single crystal structural analysis revealed that the Dy3+ ion is nine-coordinated with three N-atoms and two O-atoms from pentadentate DAPBH ligand, two O-atoms from one nitrate and other two O-atoms from two water molecules, and the coordination sphere features as a capped tetragonal antiprism in 1, while the La3+ ion is bound to six O atoms from three nitrate counter ions, three N-atoms and two O-atoms from a pentadentate DAPBH ligand to form a tricapped tetragonal antiprism coordination geometry in 2. Variable-temperature magnetic susceptibility measurements showed the existence of weak antiferromagnetic interaction in 1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1126, 15 December 2016, Pages 275-279
نویسندگان
, , ,