کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5184887 1381060 2010 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrospinning fabrication of partially crystalline bisphenol A polycarbonate nanofibers: The effects of molecular motion and conformation in solutions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Electrospinning fabrication of partially crystalline bisphenol A polycarbonate nanofibers: The effects of molecular motion and conformation in solutions
چکیده انگلیسی

Partially crystalline bisphenol A polycarbonate (BPAPC) nanofibers were successfully fabricated using a combination of a centrifugal field (1800 rpm) and an electrostatic field (25 kV). The BPAPC solution properties are key factors for adequately electrospinning the partially crystalline BPAPC nanofibers. The correlation times (τc) of methyl (τc = 9.3 ns) and of benzene-ring (τc = 15.3 and 15.8 ns) motions in the 14 wt.% BPAPC/THF solution were longer than in CH2Cl2 and CHCl3, as determined by NMR. The distribution-peak maximum of the hydrodynamic radius of BPAPC in the 14 wt.% THF solution (Rh = 15 Å) was higher than in CH2Cl2 (Rh = 9.2 Å) and CHCl3 (Rh = 7.9 Å), as evidenced by DLS data. We conclude that the BPAPC assumed a denser, more worm-like chain conformation in THF solvation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 51, Issue 13, 7 June 2010, Pages 2887-2896
نویسندگان
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