کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5201349 | 1502891 | 2015 | 20 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photo-oxidation of polymer-like amorphous hydrogenated carbon under visible light illumination
ترجمه فارسی عنوان
عکس اکسیداسیون کربن هیدروژنه آمورف مانند پلیمر مانند تحت نور قابل مشاهده است
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
کربن هیدروژنه آمورف پلیمر پلاسما، عکس اکسیداسیون، نور مرئی، سالخورده،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Amorphous hydrogenated carbon (a-C:H), a polymer-like network typically synthesized by plasma chemical vapor deposition, has long been known to exhibit optical absorption of visible light (λ > 400 nm). Here, we report that this absorption is accompanied by rapid photo-oxidation (within minutes) that behaves in most respects like classic polymer photo-oxidation with the exception that it occurs under visible light illumination rather than ultraviolet illumination. Lower plasma power during deposition produces a-C:H that is less crosslinked, is less absorptive, has longer photoluminescence lifetimes, and has a slower photo-oxidative degradation than a-C:H deposited at higher plasma power. The optical gap of the material deposited here is â¼2.5 eV, and we correspondingly observe photo-oxidation at photon energies of 2.7 and 3.1 eV. A reduced photo-oxidative response is observed at sub-gap energies, suggesting that defect states or absorption tails enable absorption at lower energies. The photo-oxidation depends on both the total accumulated dose as well as the intensity of the illumination, suggesting either a transport limitation of O2 in the a-C:H or a complex reaction pathway. Under typical laboratory lighting conditions, plasma CVD a-C:H continues to photo-oxidize for more than 20 weeks, demonstrating that any characterization of the long-term behavior of a-C:H under use conditions requires control of not only atmospheric conditions but also ambient lighting environment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 122, December 2015, Pages 133-138
Journal: Polymer Degradation and Stability - Volume 122, December 2015, Pages 133-138
نویسندگان
Salmaan Baxamusa, Ted Laurence, Matthew Worthington, Paul Ehrmann,