کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5205276 1502927 2017 28 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nuclear magnetic resonance as a powerful tool for evaluation of intermolecular interaction: Correlation with rheological measurements of recycled nanocomposite
ترجمه فارسی عنوان
رزونانس مغناطیسی هسته ای به عنوان یک ابزار قدرتمند برای ارزیابی تعامل بین مولکولی: همبستگی با اندازه گیری های رئولوژیکی نانوکامپوزیت بازیافتی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
The degradation of polystyrene nanocomposite was carried out by mechanical recycling after multiple processing of thermo-oxidative ageing. It was found that the degradation of the quaternary salt present in the clay promotes degradation of the polymer. The clay exfoliation was affected by the nanocomposite degradation process as well as the dipolar interactions of polymer chains, which influences the physical and mechanical properties of the final nanocomposite. NMR is a powerful tool for the characterization at the molecular level; it is sensitive to variations in local segmental and global movements. The correlation between NMR relaxation and rheological analyses in polymer nanocomposites was observed. This study aims to understand the complex effects of degradation in polymeric systems containing nanoparticles. Several 1H NMR relaxation parameters were analyzed. From the base line of the domain curves, the dipolar interaction phenomenon in polystyrene chains was investigated. The polymer chain heterogeneity was determined quantitatively from the MSE-FID, using a combination of Abragamian, Gaussian and exponential functions to fit experimental data. At least three domains: rigid, intermediate and mobile phases were identified based on the molecular mobilities.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 63, October 2017, Pages 417-426
نویسندگان
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