کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5228518 | 1383635 | 2008 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and characterization of novel (oligo)thienyl-imidazo-phenanthrolines as versatile Ï-conjugated systems for several optical applications Synthesis and characterization of novel (oligo)thienyl-imidazo-phenanthrolines as versatile Ï-conjugated systems for several optical applications](/preview/png/5228518.png)
A series of new heterocyclic chromophores 3-6 were synthesized in moderate to excellent yields by condensation of 5,6-phenantroline-dione with formyl-thiophene derivatives 1-2 in the presence of ammonium acetate in glacial acetic acid. These chromophores possess an (oligo)thienyl Ï-conjugated system attached to an imidazo-phenanthroline moiety. These derivatives were evaluated concerning their solvatochromic properties, thermal stabilities, and molecular optical nonlinearities.
New thermally stable heterocyclic chromophores 3-6 based on an (oligo)thiophene Ï-conjugated bridge and an imidazo-phenanthroline moiety were synthesized in moderate to excellent yields by condensation of 5,6-phenanthroline-dione with formyl (oligo)thiophenes 1-2 in the presence of ammonium acetate in glacial acetic acid.
Journal: Tetrahedron - Volume 64, Issue 39, 22 September 2008, Pages 9230-9238