کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
52418 46874 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective hydrogenation of m-dinitrobenzene to m-nitroaniline catalyzed by PVP-Ru/Al2O3
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selective hydrogenation of m-dinitrobenzene to m-nitroaniline catalyzed by PVP-Ru/Al2O3
چکیده انگلیسی

Selective hydrogenation of m-dinitrobenzene to m-nitroaniline (m-NA) catalyzed by polylvinylpyrrolidone stabilized Ru/Al2O3 (PVP-Ru/Al2O3) was studied experimentally. The effects of solvents, metal cation additives and reaction conditions were examined. The highest total yield of m-NA was obtained with 97.9% selectivity at 100% conversion when Sn4+ used as modifier (the molar ratio of m-DNB to catalyst was 477:1, the molar ratio of Sn4+ to ruthenium was 1:4) under suitable conditions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 8, Issue 9, September 2007, Pages 1305–1309
نویسندگان
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