کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5267490 1385339 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
o-(Trialkylstannyl)anilines and their utility in Migita-Kosugi-Stille cross-coupling: direct introduction of the 2-aminophenyl substituent
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
o-(Trialkylstannyl)anilines and their utility in Migita-Kosugi-Stille cross-coupling: direct introduction of the 2-aminophenyl substituent
چکیده انگلیسی
We have developed shelf- and air-stable ortho-stannylated aniline reagents that can directly be coupled with alkenyl and aryl halides via Migita-Kosugi-Stille cross-coupling. We report (i) the efficient preparation of o-(tributylstannyl)aniline (2a) and o-(trimethylstannyl)aniline (2b), (ii) the comparison of the reactivities of 2a and 2b with those of related organostannanes in cross-coupling reaction with an alkenyl halide, and (iii) the cross-coupling of 2a and 2b with a series of arylhalides and triflate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 53, Issue 37, 12 September 2012, Pages 4938-4941
نویسندگان
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