کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5270407 1385415 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of β,β′-edge fused, π-extended porphyrins and their applications in the dye-sensitized solar cells
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of β,β′-edge fused, π-extended porphyrins and their applications in the dye-sensitized solar cells
چکیده انگلیسی
Four π-extended, β,β′ aromatic ring fused porphyrins including mono- and opp-dibenzoporphyrins bearing two carboxyl groups at only one fused benzo group were synthesized. The optical results by UV-vis spectroscopy indicate that when compared with the absorption spectra of monobenzoporphyrins, greater light-harvesting capabilities can be realized for opp-dibenzoporphyrins with two benzo group at the opposite β,β′ positions of the porphyrin. The photovoltaic properties of these π-extended porphyrins were examined for the first time and the highest conversion efficiency of 1.62% was realized for opp-dibenzoporphyrin 8a-sensitized solar cell, which is ∼60% higher than that of monobenzoporphyrin 4a based solar cell indicating the effect of an extra aromatic π conjugation on the light-harvesting capabilities of π-extended porphyrins. Subsequent DFT calculation results supported our results obtained in the optical and photovoltaic studies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 54, Issue 52, 25 December 2013, Pages 7198-7201
نویسندگان
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