کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5274271 | 1385507 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Iron(III) tosylate catalyzed acylation of alcohols, phenols, and aldehydes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Iron(III) tosylate catalyzed acylation of alcohols, phenols, and aldehydes Iron(III) tosylate catalyzed acylation of alcohols, phenols, and aldehydes](/preview/png/5274271.png)
چکیده انگلیسی
Iron(III) p-toluenesulfonate (tosylate) is an efficient catalyst for acetylation of alcohols, phenols, and aldehydes. The acetylation of 1° and 2° alcohols, diols, and phenols proceeded smoothly with 2.0 mol % of catalyst. However, the reaction worked well with only a few 3° alcohols. The methodology was also applicable to the synthesis of a few benzoate esters but required the use of 5.0 mol % catalyst. Aldehydes could also be converted into the corresponding 1,1-diesters (acylals) under the reaction conditions. Iron(III) tosylate is an inexpensive, and easy to handle, commercially available catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron Letters - Volume 53, Issue 51, 19 December 2012, Pages 6946-6949
Journal: Tetrahedron Letters - Volume 53, Issue 51, 19 December 2012, Pages 6946-6949
نویسندگان
Neil J. Baldwin, Anna N. Nord, Brendan D. O'Donnell, Ram S. Mohan,