کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5400363 | 1505914 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mechanistic studies of thioxanthone-carbazole as a one-component type II photoinitiator
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Mechanistic studies of thioxanthone-carbazole as a one-component type II photoinitiator Mechanistic studies of thioxanthone-carbazole as a one-component type II photoinitiator](/preview/png/5400363.png)
چکیده انگلیسی
A mechanistic study concerning photoinitiated free radical polymerization using Thioxanthone-Carbazole (TX-Cz) as a one-component Type II photoinitiator was performed. TX-Cz presented visible initiator characteristics with absorptions at 434 and 414Â nm where the molar absorption coefficients were 2014 and 1754Â LÂ molâ1Â cmâ1, respectively. Fluorescence and phosphorescence spectroscopy, as well as laser flash photolysis was employed to study the photophysical properties of TX-Cz. In addition, photopolymerization of methyl methacrylate (MMA) showed that TX-Cz is efficient photoinitiator. To explain the initiation mechanism of TX-Cz, fluorescence and phosphorescence emission spectra of poly (methyl methacrylate) (PMMA) were also taken to see whether the initiator covalently bonded to the polymer. The postulated mechanism is based on inter- molecular reaction of the triplet, 3(TX-Cz)â with the carbazole moiety at ground state, TX-Cz. The photoinitiation efficiency of TX-Cz during gelation of multifunctional acrylates was also investigated by Photo-Differential Scanning Calorimetry (Photo-DSC) technique and high polymerization rates were obtained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 146, February 2014, Pages 424-429
Journal: Journal of Luminescence - Volume 146, February 2014, Pages 424-429
نویسندگان
Nurcan Karaca, Demet Karaca Balta, Nuket Ocal, Nergis Arsu,