کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5403605 | 1392762 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of local environment and Sm3+-codoping on the luminescence properties in the Eu3+-doped potassium tungstate phosphor for white LEDS
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of local environment and Sm3+-codoping on the luminescence properties in the Eu3+-doped potassium tungstate phosphor for white LEDS Effect of local environment and Sm3+-codoping on the luminescence properties in the Eu3+-doped potassium tungstate phosphor for white LEDS](/preview/png/5403605.png)
چکیده انگلیسی
The luminescence properties of Eu3+- and Sm3+-doped potassium tungstate phosphors were investigated. The K4â3(x+y) (WO4)2:Eux3+,Smy3+ phosphor was produced by solid-state reactions, followed by re-firing with a flux. The phosphor showed a strong absorption in the near-UV to green region due to 4f-4f electron transitions of the Eu3+ and Sm3+ ions, generating a red emission. The excitation spectrum could be adjusted by Sm3+-codoping. A small amount of Sm3+, acting as a sensitizer, increased the energy absorption peak at 405Â nm. The crystal structure and local environment around the Eu3+ ions were determined using the Rietveld method. The crystal structure of this phosphor was determined to be monoclinic with a space group of C2/c. The small Eu-0 distance in the crystal led to high energy-level splitting at the 5D0â7F2 transition of the Eu3+ ions, resulting in more emission peaks.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 128, Issue 12, December 2008, Pages 1922-1926
Journal: Journal of Luminescence - Volume 128, Issue 12, December 2008, Pages 1922-1926
نویسندگان
Gwan-Hyoung Lee, Tae-Hyung Kim, Chulsoo Yoon, Shinhoo Kang,