کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5404333 | 1392777 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Relocalization of Ce3+ 5d electrons from host conduction band
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Single crystal fibers of Ce3+ doped SrAl2O4 and CaAl4O7 were prepared through the laser heated pedestal growth method. Sites dependent Ce3+ emissions were found at 385Â nm (427Â nm) and 420Â nm (325Â nm) in SrAl2O4 and CaAl4O7 hosts, respectively. The Ce3+ emissions at 385Â nm and 420Â nm in the two hosts exhibited strong afterglows. They could persist for more than 10Â h. The long persistence and sites dependence of Ce3+ emissions were originated from charge compensation of doping Ce3+ into divalent cation sites. The lifetimes of Ce3+ emissions in both hosts were found to depend on the laser excitation wavelengths. With 266Â nm laser excitation, Ce3+ 5d electrons were delocalized into the host's conduction band, resulting in a prolonged decay time. The 355Â nm laser excitation did not delocalize the 5d electrons and hence the measured lifetimes were the intrinsic Ce3+ emission lifetimes that were 17 and 35.5Â ns in SrAl2O4 and CaAl4O7 hosts, respectively. The prolonged Ce3+ emission lifetime on 266Â nm laser excitation was because of the relocalization of the 5d electrons from the host conduction band. The lifetimes of Ce3+ 5d electrons within the conduction band were found to be 34 and 44Â ns in SrAl2O4 and CaAl4O7 hosts, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 117, Issue 2, April 2006, Pages 170-178
Journal: Journal of Luminescence - Volume 117, Issue 2, April 2006, Pages 170-178
نویسندگان
Dongdong Jia,