کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5409265 | 1506546 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Macroscopic and microscopic investigation on adsorption of Sr(II) on sericite
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Effect of water chemistry on adsorption of Sr(II) on sericite was investigated by batch techniques. The batch experiments showed that adsorption of Sr(II) on sericite significantly increased with increasing pH from 2.0 to 7.0, and then the high-level adsorption was observed at pHÂ >Â 7.0. The Sr(II) adsorption remarkably decreased with increasing ionic strength, indicating that outer-sphere surface complexation dominated the Sr(II) adsorption on sericite. The adsorption kinetics and isotherms of Sr(II) on sericite can be satisfactorily fitted by pseudo-second-order and Langmuir model, respectively. As surface complexation modeling analysis, the adsorption mechanism of Sr(II) on sericite was cation exchange and outer-sphere surface complexation at pHÂ <Â 4.0 and pHÂ >Â 5.0, respectively. These findings are crucial for the estimation of radionuclides on clay minerals at sub-environments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 225, January 2017, Pages 563-568
Journal: Journal of Molecular Liquids - Volume 225, January 2017, Pages 563-568
نویسندگان
Baowei Hu, Qingyuan Hu, Di Xu, Chengguang Chen,