کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5409512 | 1506547 | 2016 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Iodine capture by ionic liquids and recovery by compressed CO2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Ionic liquids are tunable and environmental-friendly solvents, which have been widely applied in many fields. Radioactive iodine is one of the detrimental nuclear wastes released from the nuclear weapon manufacture, nuclear energy production, and particularly nuclear accident (e.g., Chernobyl disaster in 1986 and Fukushima Daiichi nuclear accident in 2011). Here, we screen ca. 90 ionic liquids for iodine entrapment. Specifically, these ionic liquids include conventional ionic liquids, protic ionic liquids and poly-ionic liquids. Also, the effects of structural (e.g., alkyl chain, anion, cation, C2 methylation, functionalization) and external (e.g., concentration, mass) factors of ionic liquids for uptaking iodine are investigated. It is also interestingly found that recovery of iodine from iodine/ionic liquids mixture could be achieved by compressed CO2. This work could provide a guide for engineers, chemists, environmentalists or policymakers for utilization of ionic liquids for storing and recovery iodine in nuclear industry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 223, November 2016, Pages 202-208
Journal: Journal of Molecular Liquids - Volume 223, November 2016, Pages 202-208
نویسندگان
Yu Chen, Fuguang Zhang, Zhimin Xue,