کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5410023 | 1506554 | 2016 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of temperature on viscometric properties of aliphatic amino acids glycine/l-alanine/l-valine in aqueous solutions of tetraethylammonium iodide
ترجمه فارسی عنوان
اثر دما بر خواص ویسکومتریک اسید آمینه الیفاتیک گلیسین / ال-آلانین / ال-والین در محلول های آبی تترا اتیل آمونیوم یدید
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Viscosities, η, for solutions of glycine, l-alanine and l-valine in (0.03, 0.05, 0.1, 0.15 and 0.2) mol·kgâ 1 aqueous tetraethylammonium iodide (TEAI) at temperature T = (288.15, 293.15, 298.15, 303.15 and 308.15) K have been measured as a function of molality of amino acids. The viscosity B-coefficients for the amino acids in aqueous TEAI solutions have been calculated at different temperatures employing the Jones-Dole equation. The trends of variation in viscosity values of amino acids with an increase in molal concentration of TEAI solutions and also with an increase in temperature have been ascribed to the solute-solvent interactions operative in the solutions. The contribution of the solute to the activation parameters (Îμ20â, ÎH0â and ÎS0â) for viscous flow of the solution has been obtained to throw light on the mechanism of viscous flow. The contributions of the charged end group (NH3+, COOâ) and (CH2) groups of the amino acids to B-coefficient and Îμ20â have also been estimated using the linear correlations between B-coefficient or Îμ20â and the number of carbon atoms in the alkyl chains of the amino acids. All these parameters have been discussed in terms of the solute-solvent interactions in the ground and transition states.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 216, April 2016, Pages 516-525
Journal: Journal of Molecular Liquids - Volume 216, April 2016, Pages 516-525
نویسندگان
Suresh Kumar Sharma, Gurpreet Singh, Harsh Kumar, Ramesh Kataria,