کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5410086 | 1506551 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetic and isotherm parameter determination for the removal of chromium from aqueous solutions by nanoalumina, a nanoadsorbent
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Nanoalumina has been employed for the adsorption of chromium from aqueous solutions. The data for best-fit for linear and non-linear forms of kinetic and isotherm models were compared. Non-linear analysis included error analysis using 'Solver add-in' of Microsoft Excel, Origin and MATLAB software's curve fitting tool. MATLAB and Origin curve fitting tool (R2Â >Â 0.96) are better than error analysis method (0.79Â <Â R2Â >Â 0.99) of 'solver add in' for determination of isotherm parameters. Adsorption of chromium on nanoalumina is best explained by Langmuir isotherm model. Linear method is better than non-linear methods to determine the kinetic model. The sum of the square of error among linear and non-linear analysis methods for kinetic models is minimum for linear analysis method (0.008) than all other non-linear analysis methods (0.019-0.478). The adsorption of chromium on nanoalumina is governed by pseudo-second-order kinetics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 219, July 2016, Pages 1-8
Journal: Journal of Molecular Liquids - Volume 219, July 2016, Pages 1-8
نویسندگان
Shikha Dubey, Deepak Gusain, Yogesh C. Sharma,