کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5410729 | 1393383 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Micellization of polyoxyethylene-polyoxypropylene block copolymers in aqueous polyol solutions
ترجمه فارسی عنوان
میکولیزاسیون کوپلیمرهای پلی اتیلن-پلی سسی پروپیلن در محلول های پلی اتیل آبی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
The micellization of a representative polyoxyethylene-polyoxypropylene-polyoxyethylene (POE-POP-POE) amphiphilic block copolymer (Pluronic P105, EO37PO58EO37) in aqueous solutions of the common excipients glucose, glycerol or ethanol, has been investigated as a function of solute (solvent) concentration, block copolymer concentration, and temperature. The formation of POE-POP-POE micelles is favored in the presence of glucose or glycerol, while ethanol has the opposite effect. ÎH° and ÎS° values derived from analysis of critical micellization concentration (CMC) data are both positive in all mixed aqueous polyol systems. ÎH° and ÎS° decrease slightly with increasing glucose or glycerol content, but increase significantly in the presence of ethanol. A 10- to 100-fold increase of the amphiphilic block copolymer solution viscosity was observed in the presence of glucose or glycerol above a certain temperature. This viscosity increase is indicative of micelle shape changes from spherical to elongated. The CMC and viscosity changes caused by glucose and glycerol are attributed to the enhanced dehydration of the POE block of the polymeric amphiphile. Glucose is more effective than glycerol, apparently due to its higher hydration number.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 210, Part A, October 2015, Pages 20-28
Journal: Journal of Molecular Liquids - Volume 210, Part A, October 2015, Pages 20-28
نویسندگان
Kazuhiro Kaizu, Paschalis Alexandridis,