کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5411122 | 1506570 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Formation constants for the ternary complexes of vanadium(III), 8-hidroxyquinoline, and the amino acids histidine, cysteine, aspartic and glutamic acids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Formation constants for the ternary complexes of vanadium(III), 8-hidroxyquinoline, and the amino acids histidine, cysteine, aspartic and glutamic acids Formation constants for the ternary complexes of vanadium(III), 8-hidroxyquinoline, and the amino acids histidine, cysteine, aspartic and glutamic acids](/preview/png/5411122.png)
چکیده انگلیسی
Solution equilibria of V(III)-8-hydroxyquinoline (H8HQ) and aspartic acid (H2Asp), glutamic acid (H2Glu), cysteine (H2Cys) and histidine (HHis) ternary systems, have been studied through potentiometric measurements. The formation constants of the resulting mixed ligand complexes at 25 °C were calculated using 3.0 mol·dmâ 3 KCl ionic strength. The species distribution diagrams for the complexes in solution were generated considering the formation of the [V(8HQ)(H2Asp)]2 + and V(8HQ)(Asp) complexes in the vanadium(III)-H8HQ-H2Asp system. Several species were observed: [V(8HQ)(HGlu)]+, V(8HQ)(Glu) and [V(8HQ)(Glu)(OH)]â in the vanadium(III)-H8HQ-H2Glu system; species; [V(8HQ)(H2Cys)]2 +, [V(8HQ)(HCys)]+, V(8HQ)(Cys) and [V(8HQ)(Cys)(OH)]â for the vanadium(III)-H8HQ-H2Cys system, and the complexes [V(H8HQ)(HHis)]4 + and [V(8HQ)(His)]+ in the vanadium(III)-H8HQ-HHis system.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 200, Part B, December 2014, Pages 259-262
Journal: Journal of Molecular Liquids - Volume 200, Part B, December 2014, Pages 259-262
نویسندگان
Luis A. Guzmán D., José Daniel MartÃnez, Mary Lorena Araujo, Felipe Brito, Edgar del Carpio, Lino Hernández, Vito Lubes,